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Technical Paper

Advanced Aftertreatment System Meeting Future HD CNVII Legislation

2024-04-09
2024-01-2379
Options for CNVII emission legislation are being widely investigated in a national program organized by China Vehicle Emission Control Center (VECC) since early 2020. It is foreseen that this possibly last legislation in China will have more stringent emission requirements compared to CNVI, including among other changes especially a further reduction of nitrogen oxide (NOx), inclusion of nitrous oxide (N2O) and sub-23 nm particle number (PN). This study investigates the technical feasibility to fulfill a CNVII emission legislation scenario, based on a modified CNVI 8 L engine operating under both cold and hot World Harmonized Transient Cycle (WHTC) and Low Load Cycle (LLC).
Technical Paper

A Rapid Catalyst Heating System for Gasoline-Fueled Engines

2024-04-09
2024-01-2378
Increasingly stringent tailpipe emissions regulations have prompted renewed interest in catalyst heating technology – where an integrated device supplies supplemental heat to accelerate catalyst ‘light-off’. Bosch and Boysen, following a collaborative multi-year effort, have developed a Rapid Catalyst Heating System (RCH) for gasoline-fueled applications. The RCH system provides upwards of 25 kW of thermal power, greatly enhancing catalyst performance and robustness. Additional benefits include reduction of precious metal loading (versus a ‘PGM-only’ approach) and avoidance of near-engine catalyst placement (limiting the need for enrichment strategies). The following paper provides a technical overview of the Bosch/Boysen (BOB) Rapid Catalyst Heating system – including a detailed review of the system’s architecture, key performance characteristics, and the associated impact on vehicle-level emissions.
Technical Paper

System Level Simulation of H2 ICE after Treatment System

2024-04-09
2024-01-2625
Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.
Technical Paper

Humidity Controlled Evaporative Cooler for Cooling of Automotive Cabin

2024-04-09
2024-01-2580
The discussed invention is centered on the evaporative cooling of a vehicle cabin, introducing a novel concept of humidity control. Unlike conventional Air Conditioning (AC) systems that operate on the Vapor Compression Refrigeration Cycle (VCRC), which tend to be costly and contribute to higher fuel consumption due to the engine-driven compressor in automobiles, there is currently no other Original Equipment Manufacturer (OEM) fitted cabin cooling option available to address this issue. This paper introduces the idea of a humidity-controlled evaporative cooler. The objective of humidity control is achieved through a controller unit that receives feedback from a humidity sensor, subsequently regulating the operation of the water pump. The ambient air is passed through a humidified honeycomb pad, cooling through the principle of evaporation. To prevent any leftover water droplets from entering the cabin, a polyester nonwoven filter has been integrated into the system.
Technical Paper

Brake Emission Testing Process – Assuring Repeatability and Reproducibility of Emission Measurement Results

2023-11-05
2023-01-1876
Non-exhaust emissions are clearly one of the focal points for the upcoming Euro 7 legislation. The new United Nations Global Technical Regulation (UN GTR) defining the framework for brake emission measurements is about to be officially published. The first amendment to this text is already on the way through the United Nations Economic Commission for Europe (UNECE) hierarchy for decision making. In real life, the final emission factor as the ultimate result of a test is influenced by inaccuracies of numerous parts of the measurement system as well as additional contributing factors like the performance of the particulate filter handling process, which might not be primarily related to equipment specifications.
Technical Paper

Challenges of measuring low levels of CO2 and NOx on H2-ICE

2024-07-02
2024-01-2998
Society is moving towards climate neutrality where hydrogen fuelled combustion engines (H2 ICE) could be considered a main technology. These engines run on hydrogen (H2) so carbon-based emission are only present at a very low level from the lube oil. The most important pollutants NO and NO2 are caused by the exhaust aftertreatment system as well as CO2 coming from the ambient air. For standard measurement technologies these low levels of CO2 are hard to detect due to the high water content. Normal levels of CO2 are between 400-500 ppm which is very close or even below the detection limit of commonly used non-dispersive-infrared-detectors (NDIR). As well the high water content is very challenging for NOx measuring devices, like chemiluminescence detectors (CLD), where it results in higher noise and therefore a worse detection limit. Even for Fourier-transformed-infrared-spectroscopy-analysers (FT-IR) it is challenging to deal with water content over 15% without increased noise.
Technical Paper

Structural Dynamic Modelling of HVAC Systems

2024-06-12
2024-01-2923
The structure-, fluid- and air-borne excitation generated by HVAC compressors can lead to annoying noise and low frequency vibrations in the passenger compartment. These noises and vibrations are of great interest in order to maintain high passenger comfort of EV vehicles. The main objective of this paper is to develop a numerical model of the HVAC system and to simulate the structure-borne sound transmission from the compressor through the HVAC hoses to the vehicle in a frequency range up to 1 kHz. An existing automotive HVAC system was fully replicated in the laboratory. Vibration levels were measured on the compressor and on the car body side of the hoses under different operational conditions. Additional measurements were carried out using external excitation of the compressor in order to distinguish between structure- and fluid-borne transmission. The hoses were experimentally characterised with regard to their structure-borne sound transmission characteristics.
Technical Paper

Correlation of Detailed Hydrocarbon Analysis with Simulated Distillation of US Market Gasoline Samples and its Effect on the PEI-SimDis Equation of Calculated Vehicle Particulate Emissions

2023-04-11
2023-01-0298
Several predictive equations based on the chemical composition of gasoline have been shown to estimate the particulate emissions of light-duty, internal combustion engine (ICE) powered vehicles and are reviewed in this paper. Improvements to one of them, the PEISimDis equation are detailed herein. The PEISimDis predictive equation was developed by General Motor’s researchers in 2022 based on two laboratory gas chromatography (GC) analyses; Simulated Distillation (SimDis), ASTM D7096 and Detailed Hydrocarbon Analysis (DHA), ASTM D6730. The DHA method is a gas chromatography mass spectroscopy (GC/MS) methodology and provides the detailed speciation of the hundreds of hydrocarbon species within gasoline. A DHA’s aromatic species from carbon group seven through ten plus (C7 – C10+) can be used to calculate a Particulate Evaluation Index (PEI) of a gasoline, however this technique takes many hours to derive because of its long chromatography analysis time.
Technical Paper

Leveraging DOConFilter to Improve Exhaust System Packaging

2024-04-09
2024-01-2131
Diesel Particulate Filters (DPF) made of cordierite are generally used for diesel engine aftertreatment systems in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. PM/PN and NOx emission regulations will become more stringent worldwide, as represented by CARB2027 and Euro7. Technologies that can meet these strict regulations are required. As a result, aftertreatment systems have become more complex with limited space. Recently, off-highway OEMs have been interested in downsizing the aftertreatment system using concepts such as DOConFilter in an effort to reduce the size of the exhaust system. DOConFilter can effectively replace DOC + CSF or DOC + bare DPF systems with a single zone coated particulate filter. DOConFilter systems have an increased amount of coating compared to CSF as higher-filtration filters will become the norm. An undesirable increase in pressure drop is expected by adopting this new technology.
Technical Paper

Cost-Effective D-DPF Design of Aftertreatment System for Non-Road Mobile Machinery China Stage IV

2024-04-09
2024-01-2136
Since Non-Road Mobile Machinery (NRMM) China stage IV legislation has been implemented from 2022, some engines within maximum rated power between 37 to 560 kW are required for gaseous emissions, particulate matter (PM) and particulate number (PN) control, evaluated over testing cycle of Non-Road Transient Cycle (NRTC) and Non-Road Steady Cycle (NRSC). The pollutants from diesel engines, widely used in NRMM applications, can be controlled using aftertreatment systems which are comprised of a diesel oxidation catalyst (DOC) and a diesel particulate filter (DPF), or optionally a selective catalytic reduction (SCR). In this paper, a compact D-DPF design is introduced and discussed on application in harvesters, tractors, and forklifts. Because harvesters have higher exhaust gas temperature than other applications, more passive regeneration behaviors were observed. Subsequently, a compact design of DOC catalyst on DPF (D-DPF) was studied, in other words is to coat DOC catalyst on DPF.
Technical Paper

Impact of Deposit Control Additives on Particulate Emissions and Fuel Consumption in Pre-used Vehicles with Gasoline Direct Injection Engines

2024-04-09
2024-01-2127
Injector nozzle deposits can have a profound effect on particulate emissions from vehicles fitted with Gasoline Direct Injection (GDI) engines. Several recent publications acknowledge the benefits of using Deposit Control Additives (DCA) to maintain or restore injector cleanliness and in turn minimise particulates, but others claim that high levels of DCA could have detrimental effects due to the direct contribution of DCA to particulates, that outweigh the benefits of injector cleanliness. Much of the aforementioned work was conducted in laboratory scenarios with model fuels. In this investigation a fleet of 7 used GDI vehicles were taken from the field to determine the net impact of DCAs on particulates in real-world scenarios. The vehicles tested comprised a range of vehicles from different manufacturers that were certified to Euro 5 and Euro 6 emissions standards.
Technical Paper

Optimizing Carbon Monoxide Emission Reduction Using Rice Husk Activated Carbon in Automobile Exhaust Systems

2024-04-29
2024-01-5054
This research effort is to optimize the conditions to minimize carbon monoxide (CO) gas emissions utilizing activated carbon derived from rice husks, an abundant agricultural waste. In the automobile industry, addressing vehicular emissions is crucial due to environmental ramifications and stringent regulatory mandates. This study presents an innovative and potentially cost-effective solution to capture CO emissions, mainly from motorcycles. The eco-friendly nature of using rice husks and the detailed findings on optimal conditions (20 m/s gas flow rate, 0.47 M citric acid concentration, and 30 g mass of activated carbon) make this research invaluable. These conditions achieved a commendable CO adsorption rate of 54.96 ppm over 1250 s. Essentially, the insights from this research could spearhead the development of sustainable automobile exhaust systems.
Journal Article

Understanding Hydrocarbon Emissions to Improve the Performance of Catalyst-Heating Operation in a Medium-Duty Diesel Engine

2023-04-11
2023-01-0262
To cope with regulatory standards, minimizing tailpipe emissions with rapid catalyst light-off during cold-start is critical. This requires catalyst-heating operation with increased exhaust enthalpy, typically by using late post injections for retarded combustion and, therefore, increased exhaust temperature. However, retardability of post injection(s) is constrained by acceptable pollutant emissions such as unburned hydrocarbon (UHC). This study provides further insight into the mechanisms that control the formation of UHC under catalyst-heating operation in a medium-duty diesel engine, and based on the understanding, develops combustion strategies to simultaneously improve exhaust enthalpy and reduce harmful emissions. Experiments were performed with a full boiling-range diesel fuel (cetane number of 45) using an optimized five-injections strategy (2 pilots, 1 main, and 2 posts) as baseline condition.
Journal Article

A Computational Investigation of Piston Bowl Geometry Effects on PPCI-Diffusion Combustion in a Light-Duty GCI Engine

2023-04-11
2023-01-0275
A PPCI-diffusion combustion strategy has shown the potential to achieve high efficiency, clean gasoline compression ignition (GCI) combustion across the full engine operating range. By conducting a 3-D CFD-led combustion system design campaign, this investigation was focused on developing a next generation (NextGen), step-lipped piston design concept in a 2.6L advanced light-duty GCI engine. Key geometric features of the NextGen piston bowl were parametrized and studied with customized spray targeting. A low lip positioning design with 128° spray targeting was found to provide the best performance. Fuel injection strategy optimization was performed at a full-load operating point (OP), 2000 rpm/24 bar closed-cycle IMEP (IMEPcc).
Journal Article

Study on Soot Oxidation Characteristics of Ce and La Modified Pt-Pd CDPF Catalysts

2023-04-11
2023-01-0390
The catalyzed diesel particulate filter with Pt and Pd noble metals as the main loaded active components are widely used in the field of automobile engines, but the high cost makes it face huge challenges. Rare earth element doping can improve the soot oxidation performance of the catalyzed diesel particulate filter and provide a new way to reduce its cost. In this paper, thermogravimetric tests and chemical reaction kinetic calculations were used to explore the effect of Pt-Pd catalysts doped Ce, and La rare earth elements on the oxidation properties of soot. The results shown that, among Pt-Pd-5%Ce, Pt-Pd-5%La, and Pt-Pd-5%Ce-5%La catalysts, Pt-Pd-5%La catalyst has the highest soot conversion, the highest low-temperature oxidation speed, and the activation energy is the smallest. Compared with soot, this catalyst reduced T10 and T20 by 82% and 26%, respectively, meaning the catalytic activity of Pt-Pd-5%La catalyst was the best.
Journal Article

CFD Assessment of an After-Treatment System Equipped with Electrical Heating for the Reduction of the Catalyst Light-Off Time

2023-04-11
2023-01-0366
The reduction of the catalyst light-off time at the engine cold start represents a key factor for the pollutant emissions control from vehicles tested on homologation cycles and real drive conditions. The adoption of heating strategies to increase the temperature of the catalytic substrate in the early phase of the engine start is regarded as a promising solution. The present study focuses on the application of electrical heated catalyst (EHC) in an after-treatment line for a spark-ignition gasoline engine. The analysis is carried out by means of an advanced CFD framework, which includes the modeling of catalytic reactions in the substrates and accounts for the thermal evolution of all the components included in the after-treatment system.
Journal Article

New Generation Diesel Particulate Filter for Future Euro7 Regulation

2023-04-11
2023-01-0389
Diesel Particulate Filters (DPF) are becoming mandatory for many Heavy Duty Vehicle (HDV) and Non Road Mobile Machinery (NRMM) applications as the requirement for particulate filtration performance has increased over this past decade. In a previous study, a new generation of cordierite DPF was developed to meet the latest major emission regulations; PN-PEMS requirement for EuroVI StepE, while maintaining a lower pressure drop and high ash capacity. Despite the improvements made in the latest generation DPF material, the introduction of tighter particulate regulations demands further improvement in DPF technology. More specifically, PN emission limits for Euro7 under wide operation conditions in conjunction with PN down to 10nm, as described in the proposal from Consortium for Ultra Low Vehicle Emission (CLOVE), requires further improvement in PN filtration performance. Pressure drop, which may negatively influence the CO2 emissions, remains a key performance criteria.
Journal Article

Laboratory sulfation of an ammonia slip catalyst with a real-world SO2 concentration

2023-04-11
2023-01-0380
Upcoming, stricter diesel exhaust emissions standards will likely require aftertreatment architectures with multiple diesel exhaust fluid (DEF) introduction locations. Managing NH3 slip with technologies such as an ammonia slip catalyst (ASC) will continue to be critical in these future aftertreatment systems. In this study, we evaluate the impact of SO2 exposure on a state-of-the-art commercially available ASC. SO2 is co-fed at 0.5 or 3 ppmv to either approximate or accelerate a real-world exhaust SO2 impact. ASC performance during sulfur co-feeding is measured under a wide variety of simulated real-world conditions. Results indicate that the loss of NO conversion during SCR is dependent on the cumulative SO2 exposure, regardless of the inlet SO2 concentration. Meanwhile, N2O formation under SCR conditions is nonlinearly affected by SO2 exposure, with formation increasing during 0.5 ppmv SO2 exposure but decreasing in the presence of 3 ppmv SO2.
Technical Paper

The Development of a Zeolite-Based Cold-Start Catalyst (CSC) for China 6b Vehicles (Conventional & Hybrid) to Meet the Next Chinese Vehicle Emission Standard, Part II

2024-04-09
2024-01-2656
This is a follow-up report about the development of a cost-effective Palladium (Pd) zeolite-based (HC/NOx trap type) cold-start catalyst (CSC) [1] to meet the future more stringent Chinese vehicle tailpipe emission standard. The impacts of Pd /stabilizer combination within zeolite for the HC/NOx trapping efficiency, the high temperature aging and the durability of the CSCs will be demonstrated by the laboratory results within this paper. The feasibility of a Cu zeolite, a popular non-precious metal ion- zeolite CSC for vehicle applications with respect to cost saving options will be demonstrated. A more complete picture of the effects of PGM/stabilizer within the zeolite to the functions of a CSC will also be summarized in this paper. All results indicate clearly that without the PGM/stabilizer within the zeolite, it would be difficult for the zeolite-based HC/NOx trap type CSC catalyst to be practically used for a vehicle application.
Technical Paper

Electric Vehicle Modeling: Advanced Torque Split Analysis across Different Architectures

2024-04-09
2024-01-2166
The proliferation of electric vehicles (EVs) is resulting in a big transition in the automotive industry, with the goal of reducing greenhouse gas emissions and improving energy efficiency. There are a variety of different architectural configurations and power distribution strategies that can be optimized for drivability performance, all-electric range, and overall efficiency. This paper describes the efforts of the research team in exploring different EV architectures to better understand their impacts on system performance in terms of energy efficiency and vehicle drivability. In search for an ideal powertrain architecture for a shared-use EV, the research team conducted a comprehensive analysis of a various EV architectures (including RWD and AWD) with different motor parameters, considering a spectrum of targeted vehicle technology specifications such as acceleration and braking performance, and fuel economy.
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